A study of nanostructure assemblies and guest-host interactions in sodium zeolite-Y using 23Na double-rotation NMR

Date

1991-12-01

Author

Jelinek, R.
Pines, A.
Özkar, Saim
Ozin, G.A.

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23Na double-rotation NMR (DOR) spectroscopy provides details on site-specific adsorption of various molecular guests within the nanometer-dimension void spaces of sodium zeolite-Y. Anchoring of hexacarbonyl metal(0) precursors, as well as their molecular metal oxide photooxidation products, to specific extraframework sodium cation sites, is readily detected by 23Na DOR. Loading-dependent chemical shifts and line-shape alterations yield useful information on the structure, bonding and organization of the guests within the zeolite host lattice.

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=36149035789&origin=inward
https://hdl.handle.net/11511/102645

Journal

Nanotechnology

DOI

https://doi.org/10.1088/0957-4484/2/4/003

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

R. Jelinek, A. Pines, S. Özkar, and G. A. Ozin, “A study of nanostructure assemblies and guest-host interactions in sodium zeolite-Y using 23Na double-rotation NMR,” Nanotechnology, vol. 2, no. 4, pp. 182–186, 1991, Accessed: 00, 2023. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=36149035789&origin=inward.