Kesterite Films Processed with Organic Solvents: Unveiling the Impact of Carbon-Rich Fine-Grain-Layer Formation on Solar-Cell Performance

Date

2024-01-01

Author

Javed, Ahmed
Donmez, Doguscan
Jones, Michael D. K.
Qu, Yongtao
Günbaş, Emrullah Görkem
Yerci, Selçuk

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Solution-processed kesterite (copper zinc tin sulfide [CZTS]) solar cells attract significant attention owing to their low cost, ease of large-scale production, and earth-abundant elemental composition, which make these devices promising to fulfill the ever-increasing demand of the photovoltaic (PV) industry. Compared to the performances of expensive vacuum-based techniques, colloidal nanocrystal kesterite solar cells garner substantial interest due to their economical and rapid processing. Led by the hot-injection method, organic solvent-based techniques are widely adopted to realize CZTS nanocrystal inks. With organic solvents, ligand-stabilized nanoparticles are formed leading to dispersive and homogenous kesterite inks. However, the presence of carbon-rich ligands around the nanocrystal surface often leads to the formation of a fine-grain layer that is rich in carbon content. The organic ligands decompose into amorphous carbon residues during a high-temperature annealing process and hinder the grain growth process. The carbon-rich fine-grain (CRFG) layer generally poses a negative influence on the PV performance of the kesterite solar cell; however, few reports maintain their disposition about CRFG as innocuous. In this review study, a detailed discussion on CRFG is presented, aiming to understand the insights about its formation and impact on the device's performance.

Subject Keywords

carbon-rich, fine-grain, kesterites, nanocrystals, organic solvents

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85197408985&origin=inward
https://hdl.handle.net/11511/110244

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Department of Chemistry, Article