Zinc Chalcogenide Based Shell Layers for Colloidal Quantum Wells

Date

2025-01-01

Author

Aldemir, Cagatay Han
Yazici, Ahmet Faruk
Ergezer, Nehir
Korkmaz, Taha Can
Mutlugun, Evren
Keleştemur, Yusuf

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Colloidal quantum wells, also known as colloidal nanoplatelets (NPLs), have emerged as a promising class of materials for light-emitting devices (LEDs). However, the most widely studied core/shell NPLs, which rely on cadmium-based shell layers, face challenges due to toxicity concerns and improper charge confinement. To address these limitations, a new synthetic approach is presented that enables the controlled growth of zinc chalcogenide-based shell layers on NPLs. The synthesized CdSe/ZnSe core/shell NPLs exhibit emission between 615 and 630 nm, with a moderate photoluminescence quantum yield (PL-QY) of 40–50%. It is also demonstrated that the lateral dimensions of the CdSe core NPLs significantly affect the optical properties of the core/shell heterostructures, with smaller lateral dimensions resulting in narrower emission linewidths as low as 20 nm. Further passivation of these core/shell NPLs with an additional ZnS shell layer significantly increases the PL-QY up to 80–90%. Finally, the device performance of these two core/shell NPLs is investigated by fabricating solution-processed LEDs. With LEDs incorporating CdSe/ZnSe/ZnS core/multi-shell NPLs as the active light-emitting layer, an external quantum efficiency (EQE) of 3.82% and a maximum brightness of 6477 cd m−2 is obtained. These findings underscore the significant potential of zinc chalcogenide-based shell layers in advancing colloidal NPLs toward high-performance light-emitting devices.

Subject Keywords

colloidal nanoplatelets, colloidal quantum wells, colloidal semiconductor nanocrystals, core shell heterostructures, light-emitting devices

URI

https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105003802255&origin=inward
https://hdl.handle.net/11511/114852

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Department of Metallurgical and Materials Engineering, Article