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Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole
Date
2004-12-31
Author
Yilmaz, F.
Sel, O.
Guner, Y.
Toppare, Levent Kamil
Hepuzer, Y.
Yagci, Y.
Metadata
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This paper reports on the synthesis of conducting polypyrrole and polythiophene grafted block copolymers of methylmethacrylate (MMA) and 3-methylthienylmethacrylate (MTM) by a multi-step process. For this purpose, block copolymers of MMA and MTM were prepared by controlled radical polymerization using 1,1-diphenylethene (DPE). Subsequently, polypyrrole and polythiophene sequences were grafted onto these block copolymers by constant potential electrolysis.
Subject Keywords
poly(metbylmethacrylate-b-3-methylthienylmethactylate)
,
Electrochemical grafting
,
Conducting copolymers
,
Diphenylethene
URI
https://hdl.handle.net/11511/28346
Journal
Journal of Macromolecular Science, Part A
DOI
https://doi.org/10.1081/ma-120028475
Collections
Department of Chemistry, Article
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F. Yilmaz, O. Sel, Y. Guner, L. K. Toppare, Y. Hepuzer, and Y. Yagci, “Controlled Synthesis of Block Copolymers Containing Side Chain Thiophene Units and Their Use in Electrocopolymerization with Thiophene and Pyrrole,”
Journal of Macromolecular Science, Part A
, pp. 401–418, 2004, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/28346.