Configuration of the Diels–Alder Adduct of Hexachlorocyclopentadiene withL-Menthyl Acrylate

1997-7-15
Ülkü, D.
Tahir, M. N.
Demir, A. S.
Akhmedov, I.
Tanyeli, Cihangir
The structure of the title compound, endo-(2R)-(-)-L-menthyl 1,4,5,6,7,7-hexachloro-4-norbornene-2-carboxylate, consists of discrete C18H22CL6O2 molecules related by a twofold screw axis. The relative configuration was determined and the chirality at the unknown centres was assigned on the basis of the known chiral centres of L-menthene. Both the average Csp(2)-Cl, 1.689(5), and Csp(3)-Cl, 1.753(3) Angstrom, distances are a little shorter than the literature values. The six-membered ring of the L-menthyl group has a chair conformation. C-O bond lengths in the carboxylate group are 1.194(7) and 1.323(7) Angstrom.
Acta Crystallographica Section C Crystal Structure Communications

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Citation Formats
D. Ülkü, M. N. Tahir, A. S. Demir, I. Akhmedov, and C. Tanyeli, “Configuration of the Diels–Alder Adduct of Hexachlorocyclopentadiene withL-Menthyl Acrylate,” Acta Crystallographica Section C Crystal Structure Communications, pp. 899–901, 1997, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/28394.