Bis[5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylato]copper(II) dihydrate

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2011-10-29
Kudryavtsev, Konstantin V.
Churakov, Andrei V.
Doğan, Özdemir
In the title compound, [Cu(C16H19BrNO4)(2)]center dot 2H(2)O, the Cu-II ion resides on an inversion centre and is coordinated by two O and two N atoms from two enantiomeric 5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the molecules into layers parallel to the bc plane. The crystal studied was twinned by pseudomerohedry with twin fractions of 0.719 (3) and 0.281 (3).

Citation Formats
K. V. Kudryavtsev, A. V. Churakov, and Ö. Doğan, “Bis[5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylato]copper(II) dihydrate,” Acta Crystallographica Section E Structure Reports Online, vol. 67, no. 11, pp. m1623–m1623, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/28410.