Bis[5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylato]copper(II) dihydrate

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2011-10-29

Author

Kudryavtsev, Konstantin V.
Churakov, Andrei V.
Doğan, Özdemir

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In the title compound, [Cu(C16H19BrNO4)(2)]center dot 2H(2)O, the Cu-II ion resides on an inversion centre and is coordinated by two O and two N atoms from two enantiomeric 5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the molecules into layers parallel to the bc plane. The crystal studied was twinned by pseudomerohedry with twin fractions of 0.719 (3) and 0.281 (3).

Subject Keywords

Single-crystal X-ray study, T = 150 K, Mean (C–C) = 0.013 A˚, R factor = 0.066, WR factor = 0.161, Data-to-parameter ratio = 15.0

URI

https://hdl.handle.net/11511/28410

Journal

Acta Crystallographica Section E Structure Reports Online

DOI

https://doi.org/10.1107/s1600536811043893

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Department of Chemistry, Article

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Citation Formats

K. V. Kudryavtsev, A. V. Churakov, and Ö. Doğan, “Bis[5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylato]copper(II) dihydrate,” Acta Crystallographica Section E Structure Reports Online, pp. m1623–m1623, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/28410.