ELECTROINITIATED POLYMERIZATION OF N-VINYLCARBAZOLE BY DIRECT ELECTRON-TRANSFER

Date

1990-01-01

Author

SACAK, M
Akbulut, Ural
HACIOGLU, B

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Electroinitiated polymerization of N-vinylcarbazole has been accomplished by constant potential electrolysis. It was found that direct electron transfer from the monomer to the anode initiates the polymerization even at a potential as low as +0.95 V versus Ag−/ Ag+. Dichloromethane was used as the solvent, and the electrolyte was tetrabutylammonium fluoroborate. Conversions as high as 86% were reached even when a microelectrode was used. Effects of electrode area, temperature, and electrode potential on polymerization were studied. Percent conversion was followed by cyclic voltammetry.

URI

https://hdl.handle.net/11511/32874

Journal

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY

DOI

https://doi.org/10.1080/00222339009349674

Collections

Department of Chemistry, Article

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Citation Formats

M. SACAK, U. Akbulut, and B. HACIOGLU, “ELECTROINITIATED POLYMERIZATION OF N-VINYLCARBAZOLE BY DIRECT ELECTRON-TRANSFER,” JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, pp. 1041–1052, 1990, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/32874.