Show/Hide Menu
Hide/Show Apps
anonymousUser
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Açık Bilim Politikası
Açık Bilim Politikası
Frequently Asked Questions
Frequently Asked Questions
Browse
Browse
By Issue Date
By Issue Date
Authors
Authors
Titles
Titles
Subjects
Subjects
Communities & Collections
Communities & Collections
ELECTROINITIATED POLYMERIZATION OF N-VINYLCARBAZOLE BY DIRECT ELECTRON-TRANSFER
Date
1990-01-01
Author
SACAK, M
Akbulut, Ural
HACIOGLU, B
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
4
views
0
downloads
Electroinitiated polymerization of N-vinylcarbazole has been accomplished by constant potential electrolysis. It was found that direct electron transfer from the monomer to the anode initiates the polymerization even at a potential as low as +0.95 V versus Ag−/ Ag+. Dichloromethane was used as the solvent, and the electrolyte was tetrabutylammonium fluoroborate. Conversions as high as 86% were reached even when a microelectrode was used. Effects of electrode area, temperature, and electrode potential on polymerization were studied. Percent conversion was followed by cyclic voltammetry.
URI
https://hdl.handle.net/11511/32874
Journal
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY
DOI
https://doi.org/10.1080/00222339009349674
Collections
Department of Chemistry, Article