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New phosphine oxide aziridinyl phosphonates as chiral Lewis bases for the Abramov-type phosphonylation of aldehydes
Date
2013-05-31
Author
Doğan, Özdemir
Isci, Muhammet
Aygun, Muhittin
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A series of Lewis bases were screened for Abramov-type phosphine additions to aldehydes. A novel phosphine oxide aziridinyl phosphonate POAP-A was found to be better than the others in forming the product in 96% yield and with 42% ee. The absolute configuration of the newly synthesized POAP Lewis bases was determined by single-crystal X-ray analysis.
Subject Keywords
Physical and Theoretical Chemistry
,
Inorganic Chemistry
,
Organic Chemistry
,
Catalysis
URI
https://hdl.handle.net/11511/35355
Journal
TETRAHEDRON-ASYMMETRY
DOI
https://doi.org/10.1016/j.tetasy.2013.04.005
Collections
Department of Chemistry, Article
Citation Formats
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BibTeX
Ö. Doğan, M. Isci, and M. Aygun, “New phosphine oxide aziridinyl phosphonates as chiral Lewis bases for the Abramov-type phosphonylation of aldehydes,”
TETRAHEDRON-ASYMMETRY
, vol. 24, pp. 562–567, 2013, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/35355.