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The effect of para- and meta-substituted fluorine on optical behavior of benzimidazole derivatives
Date
2013-10-30
Author
Ileri, Merve
Hacioglu, Serife O.
Toppare, Levent Kamil
Metadata
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Design, synthesis, and electrochemical properties of two novel donor-acceptor-donor type benzimidazole and thiophene based monomers; 2-(4-fluorophenyl)-4,7-di(thiophen-2-yl)-1H-benzo[d]imidazole (BIPF) and 2-(3-fluorophenyl)-4,7-di(thiophen-2-yl)-1H-benzo[d]imidazole (BIMF) were highlighted. The position of fluorine as a substituent was varied from para- to meta- in order to investigate position effects on the electrochemical and optical properties of electrochemically synthesized polymers. Both polymers were p type dopable and they can be switched between orange and blue color during p-doping/dedoping. Significant improvements in the percent transmittance for PBIMF were observed compared to similar molecules in literature.
Subject Keywords
Electrochromism
,
Donor-acceptor
,
Substitution effect
,
Fluorine
URI
https://hdl.handle.net/11511/36043
Journal
ELECTROCHIMICA ACTA
DOI
https://doi.org/10.1016/j.electacta.2013.07.102
Collections
Department of Chemistry, Article
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M. Ileri, S. O. Hacioglu, and L. K. Toppare, “The effect of para- and meta-substituted fluorine on optical behavior of benzimidazole derivatives,”
ELECTROCHIMICA ACTA
, pp. 214–220, 2013, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36043.