Umpolung strategy: Advances in catalytic C-C bond formations

Date

2013-01-01

Author

EYMUR, Serkan
GÖLLÜ, Mehmet
Tanyeli, Cihangir

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This mini-review examines the recent advances in umpolung strategy, devised originally by Corey and Seebach. Although numerous stoichiometric variants have been published to date, this article covers just the catalytic C-C bond forming reactions due to their major benefits such as atom economy, less pollution, and workable simplicity. In the context of umpolung, the studies are evaluated under 3 main titles: enzyme, N -heterocyclic carbene, and cyanide ion catalyzed reactions. In particular, enzyme and NHC catalyzed reactions mainly involve asymmetric applications.

Subject Keywords

Umpolung, Thiamine pyrophosphate (TPP), N -heterocyclic carbene, Asymmetric synthesis

URI

https://hdl.handle.net/11511/36069

Journal

TURKISH JOURNAL OF CHEMISTRY

DOI

https://doi.org/10.3906/kim-1303-85

Collections

Department of Chemistry, Article

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Citation Formats

S. EYMUR, M. GÖLLÜ, and C. Tanyeli, “Umpolung strategy: Advances in catalytic C-C bond formations,” TURKISH JOURNAL OF CHEMISTRY, pp. 586–609, 2013, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/36069.