Structure-property relations in donor-acceptor-donor type benzimidazole containing conjugated polymers

Date

2014-01-01

Author

ZAIFOGLU, Buket
HACIOGLU, Serife O.
UNLU, Naime A.
Çırpan, Ali
Toppare, Levent Kamil

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In order to gain deeper insight about structure-property relations properties, two novel donor-acceptor-donor type monomers were studied. 4'-Tert-butyl-4,7-di(thiophen-2-yl)spiro[benzo[d]imidazole-2,1'-cyclohexane] and 4,7di(2,2'-bithiophen-5-yl)-4'-tert-butylspiro[benzo[d]imidazole-2,1'-cyclohexane] were synthesized and electrochemically polymerized. Electrochemical and optical properties of the polymers were investigated via cyclic voltammetry and UV-Vis-NIR spectroscopy techniques. It was found that changing donor unit from thiophene to bithiophene results in a drastic change in optical and electrochemical properties, especially in optical contrast.

Subject Keywords

Mechanical Engineering, General Materials Science, Mechanics of Materials

URI

https://hdl.handle.net/11511/42084

Journal

JOURNAL OF MATERIALS SCIENCE

DOI

https://doi.org/10.1007/s10853-013-7696-8

Collections

Department of Chemistry, Article

Citation Formats

B. ZAIFOGLU, S. O. HACIOGLU, N. A. UNLU, A. Çırpan, and L. K. Toppare, “Structure-property relations in donor-acceptor-donor type benzimidazole containing conjugated polymers,” JOURNAL OF MATERIALS SCIENCE, vol. 49, no. 1, pp. 225–231, 2014, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/42084.