Impedance spectroscopy of N-substituted oligo-oxyethylene polypyrrole films

Date

2008-05-15

Author

CİHANER, ATİLLA
Önal, Ahmet Muhtar

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The electrochemical properties of neutral (dedoped) and oxidized (doped) poly(1,11-bis(1,1-pyrrole)-3,6,9-trioxaundecane) (poly-I) film electrodes were investigated using cyclic voltammetry and electrochemical impedance spectroscopy (EIS) techniques. Poly-I was deposited on glassy carbon electrode (GCE) from acetonitrile solution containing 5.0 x 10(-3) M 1,11-bis(1,1-pyrrole)-3,6,9-trioxaundecane (I) and 0.1 M LiClO4 supporting electrolyte. Doped poly-I exhibits a single semicircle in its complex-capacitance plots, indicating a single dominant ion transport process, together with high capacitance values. These features make this polymer film a candidate for an energy storage material. Also, poly-I can be a candidate as a sensory material for the detection of Ag+ based on impedance parameters. (C) 2008 Wiley Periodicals, Inc.

Subject Keywords

Materials Chemistry, General Chemistry, Surfaces, Coatings and Films, Polymers and Plastics

URI

https://hdl.handle.net/11511/46931

Journal

JOURNAL OF APPLIED POLYMER SCIENCE

DOI

https://doi.org/10.1002/app.27732

Collections

Department of Chemistry, Article

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Citation Formats

A. CİHANER and A. M. Önal, “Impedance spectroscopy of N-substituted oligo-oxyethylene polypyrrole films,” JOURNAL OF APPLIED POLYMER SCIENCE, pp. 2373–2378, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/46931.