Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine-borane

Date

2010-01-01

Author

Zahmakiran, Mehmet
Tristany, Mar
Philippot, Karine
Fajerwerg, Katia
Özkar, Saim
Chaudret, Bruno

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The preparation of Ru(0) nanoclusters stabilized by 3-aminopropyltriethoxysilane and their characterization by a combination of complementary techniques are described. These new Ru(0) nanoclusters provide high activity and unprecedented reusability as a heterogeneous catalyst in the dehydrogenation of dimethylamine-borane.

Subject Keywords

Boron-Ntroigen bonds, Hydrogen Storage, Amine-Borane, Thermal-Decomposition, Homogeneous Catalysis, Ammonia-Borane, Nanoparticles, Complexes, Adducts, Aminoboranes

URI

https://hdl.handle.net/11511/48817

Journal

CHEMICAL COMMUNICATIONS

DOI

https://doi.org/10.1039/c000419g

Collections

Department of Chemistry, Article

Citation Formats

M. Zahmakiran, M. Tristany, K. Philippot, K. Fajerwerg, S. Özkar, and B. Chaudret, “Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine-borane,” CHEMICAL COMMUNICATIONS, vol. 46, no. 17, pp. 2938–2940, 2010, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/48817.