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Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine-borane
Date
2010-01-01
Author
Zahmakiran, Mehmet
Tristany, Mar
Philippot, Karine
Fajerwerg, Katia
Özkar, Saim
Chaudret, Bruno
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
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The preparation of Ru(0) nanoclusters stabilized by 3-aminopropyltriethoxysilane and their characterization by a combination of complementary techniques are described. These new Ru(0) nanoclusters provide high activity and unprecedented reusability as a heterogeneous catalyst in the dehydrogenation of dimethylamine-borane.
Subject Keywords
Boron-Ntroigen bonds
,
Hydrogen Storage
,
Amine-Borane
,
Thermal-Decomposition
,
Homogeneous Catalysis
,
Ammonia-Borane
,
Nanoparticles
,
Complexes
,
Adducts
,
Aminoboranes
URI
https://hdl.handle.net/11511/48817
Journal
CHEMICAL COMMUNICATIONS
DOI
https://doi.org/10.1039/c000419g
Collections
Department of Chemistry, Article