Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine-borane

Date

2010-01-01

Author

Zahmakiran, Mehmet
Tristany, Mar
Philippot, Karine
Fajerwerg, Katia
Özkar, Saim
Chaudret, Bruno

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The preparation of Ru(0) nanoclusters stabilized by 3-aminopropyltriethoxysilane and their characterization by a combination of complementary techniques are described. These new Ru(0) nanoclusters provide high activity and unprecedented reusability as a heterogeneous catalyst in the dehydrogenation of dimethylamine-borane.

Subject Keywords

Boron-Ntroigen bonds, Hydrogen Storage, Amine-Borane, Thermal-Decomposition, Homogeneous Catalysis, Ammonia-Borane, Nanoparticles, Complexes, Adducts, Aminoboranes

URI

https://hdl.handle.net/11511/48817

Collections

Department of Chemistry, Article