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Iron(III) trifluoroacetate [Fe(O2CCF3)3] catalyzed epoxide opening with amines
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10.3998ark.5550190.0009.218.pdf
Date
2008-1-27
Author
Erturk, Erkan
Demir, Ayhan S.
Metadata
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Non-hygroscopic, non-toxic, and readily available iron(III) trifluoroacetate [Fe(O2CCF3)(3)] was found to be a highly regioselective catalyst for the ring opening of a wide variety of epoxides with diverse amines under solvent-free conditions. The stereospecific ring opening of (R)-styrene oxide (4) with p-anisidine (2b) in the presence of 1 mol% of Fe(O2CCF3)(3) gave 2-(p-methoxyphenyl-amino)-2-phenylethanol (5b) in enantiopure form (> 99 % ee) within 60 minutes.
Subject Keywords
Epoxide
,
Epoxide opening
,
Amino alcohol
,
Iron
,
Solvent-free
,
Green chemistry
URI
https://hdl.handle.net/11511/50983
Journal
Arkivoc
DOI
https://doi.org/10.3998/ark.5550190.0009.218
Collections
Department of Chemistry, Article
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E. Erturk and A. S. Demir, “Iron(III) trifluoroacetate [Fe(O2CCF3)3] catalyzed epoxide opening with amines,”
Arkivoc
, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/50983.