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Remarkable phosphodiester hydrolysis activity of a novel Ce-IV complex in neutral aqueous solutions
Date
1999-09-08
Author
Baykal, U
Akkaya, Mahinur
Akkaya, EU
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
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A novel Ce-IV-complex of 1,4,7-tris(carbamoylmethyl)-1,4,7-triazacyclononane has been synthesized. The complex is both stable in aqueous solutions at neutral pH and very efficient in promoting the hydrolysis of a phosphodiester model compound and yeast tRNA(phe). The RNA model compound, 2-hydroxypropyl-p-nitrophenylphosphate hydrolysis is accelerated 7400-fold at pH 7.5, as a result of an unprecedented hydrolytic activity.
Subject Keywords
Phosphodiester hydrolysis
,
Artificial enzymes
,
Lanthanide complexes
,
RNA cleavage
URI
https://hdl.handle.net/11511/51793
Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
DOI
https://doi.org/10.1016/s1381-1169(99)00160-0
Collections
Graduate School of Natural and Applied Sciences, Article