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Transition metal compound mediated reduction of alpha-amino acids to 1,2-amino alcohols with NaBH4 in water
Date
1999-01-01
Author
Demir, Ayhan Sıtkı
Akhmedov, IM
Sesenoglu, O
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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A new efficient and cost-effective method for the preparation of 1,2-amino alcohols is described. The reactions of amino acids with NaBH4 in the presence of NiCl2 or MoO3 in water give 1,2-amino alcohols in high yield. When optically pure amino acids were used, optically pure 1,2-amino alcohols were obtained.
Subject Keywords
O-alkyl ethers
,
Sodıum-borohydrıde
,
Enantıoselectıve reductıon
,
Asymmetric-synthesis
,
Salt systems
,
Hydrogenation
,
Derivatives
,
Convenİent
,
Chloride
,
Ketones
URI
https://hdl.handle.net/11511/55226
Journal
TURKISH JOURNAL OF CHEMISTRY
Collections
Department of Chemistry, Article