Transition metal compound mediated reduction of alpha-amino acids to 1,2-amino alcohols with NaBH4 in water

Date

1999-01-01

Author

Demir, Ayhan Sıtkı
Akhmedov, IM
Sesenoglu, O

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

12
views

0
downloads

A new efficient and cost-effective method for the preparation of 1,2-amino alcohols is described. The reactions of amino acids with NaBH4 in the presence of NiCl2 or MoO3 in water give 1,2-amino alcohols in high yield. When optically pure amino acids were used, optically pure 1,2-amino alcohols were obtained.

Subject Keywords

O-alkyl ethers, Sodıum-borohydrıde, Enantıoselectıve reductıon, Asymmetric-synthesis, Salt systems, Hydrogenation, Derivatives, Convenİent, Chloride, Ketones

URI

https://hdl.handle.net/11511/55226

Journal

TURKISH JOURNAL OF CHEMISTRY

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

Bifunctional Silicotungstic Acid and Tungstophosphoric Acid Impregnated Cu-Zn-Al & Cu-Zn-Zr Catalysts for Dimethyl Ether Synthesis from Syngas Karaman, Birce Pekmezci; OKTAR, NURAY; DOĞU, GÜLŞEN; Doğu, Timur (2020-09-01) In the present study, a set of methanol synthesis catalysts with different Cu/Zn/Al or Cu/Zn/Zr molar ratios were synthesized by a co-precipitation method. Silicotungstic acid and tungstophosphoric acid were impregnated into these materials to synthesize new bifunctional catalytic materials to be used in direct synthesis of dimethyl ether (DME) from syngas. In the case of methanol production, synthesized Cu/Zn/Al catalysts exhibited quite high methanol selectivity, reaching to approximately 87%. These resul...
Chain-extended bismaleimides .1. Preparation and characterization of maleimide-terminated resins Yerlikaya, Z; Oktem, Z; Bayramlı, Erdal (1996-01-03) Starting from aromatic diamines, a series of bismaleimides (BMIs) and maleimide-terminated structural resins were prepared in solution and characterized. Maleimide-terminated resins were prepared through Michael addition reaction with 3/2 molar ratio of bismaleimide and aromatic diamine as reactants. The structural analysis was performed by FTIR and H-1-NMR spectroscopy. Thermal properties are investigated by TGA, DTA, and DSC. Number-average molecular-weights of the resins were determined by cryoscopy. The...
Mixed alpha-Fe2O3/Bi2WO6 oxides for photoassisted hetero-Fenton degradation of Methyl Orange and Phenol Jaramillo-Paez, C.; Navio, J. A.; Hidalgo, M. C.; Bouzıanı, Asmae; El Azzouzi, Mohammed (2017-01-01) Mixed oxides, alpha-Fe2O3/Bi2WO6, were prepared using a mechanical mixing procedure by adding to the Bi2WO6 previously obtained by hydrothermal method the corresponding amount of a prepared alpha-Fe2O3, the latter obtained by thermal decomposition of Fe(NO3)center dot 9H(2)O. The physicochemical surface, structural, morphological characteristics and optical properties of the samples, single and mixed, were determined by BET, XRD, FE-SEM, XPS and UV-vis diffuse reflectance spectroscopy. UV-vis diffuse reflec...
Simple, mild, and efficient method for the reduction of 1,4-benzoquinones to hydroquinones by the action of NaN3 Algi, Fatih; Balcı, Metin (Informa UK Limited, 2006-08-01) A simple, mild, and efficient method is presented for the reduction of 1,4-benzoquinones to hydroquinones by the action of NaN3 under neutral conditions in the presence of water.
Dimethyl Ether Synthesis over Novel Silicotungstic Acid Incorporated Nanostructured Catalysts Ciftci, Aysegul; VARIŞLI, DİLEK; Doğu, Timur (2010-01-01) Dimethyl ether (DME), which is an excellent green diesel-fuel alternate with excellent clean burning properties, is synthesized by dehydration of methanol over novel solid acid catalysts, which are synthesized following a direct hydrothermal route and using silicotungstic acid (STA) as the active compound. These mesoporous silicate structured catalysts have surface area values of 108-393 m(2)/g, depending upon their W/Si ratio. These catalysts showed very high methanol dehydration activity and also very hig...

Citation Formats

A. S. Demir, I. Akhmedov, and O. Sesenoglu, “Transition metal compound mediated reduction of alpha-amino acids to 1,2-amino alcohols with NaBH4 in water,” TURKISH JOURNAL OF CHEMISTRY, pp. 123–126, 1999, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55226.