Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds

2001-06-01
Zora, Metin
Herndon, JW
Li, YH
Rossi, J
The coupling of a variety of transition metal-carbene complexes with alkynols has been studied. In many cases, the intermediate vinylcarbene complexes formed in this reaction undergo a ring expansion to afford cyclic ketone derivatives. This scope and limit of this process is explored.
Citation Formats
M. Zora, J. Herndon, Y. Li, and J. Rossi, “Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds,” TETRAHEDRON, vol. 57, no. 24, pp. 5097–5107, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55530.