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Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds
Date
2001-06-01
Author
Zora, Metin
Herndon, JW
Li, YH
Rossi, J
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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The coupling of a variety of transition metal-carbene complexes with alkynols has been studied. In many cases, the intermediate vinylcarbene complexes formed in this reaction undergo a ring expansion to afford cyclic ketone derivatives. This scope and limit of this process is explored.
Subject Keywords
Ring expansion
,
Carbene complexes
,
Alkynols
URI
https://hdl.handle.net/11511/55530
Journal
TETRAHEDRON
DOI
https://doi.org/10.1016/s0040-4020(01)00359-3
Collections
Department of Chemistry, Article