Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds

Date

2001-06-01

Author

Zora, Metin
Herndon, JW
Li, YH
Rossi, J

Metadata

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The coupling of a variety of transition metal-carbene complexes with alkynols has been studied. In many cases, the intermediate vinylcarbene complexes formed in this reaction undergo a ring expansion to afford cyclic ketone derivatives. This scope and limit of this process is explored.

Subject Keywords

Ring expansion, Carbene complexes, Alkynols

URI

https://hdl.handle.net/11511/55530

Journal

TETRAHEDRON

DOI

https://doi.org/10.1016/s0040-4020(01)00359-3

Collections

Department of Chemistry, Article

Citation Formats

M. Zora, J. Herndon, Y. Li, and J. Rossi, “Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds,” TETRAHEDRON, vol. 57, no. 24, pp. 5097–5107, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55530.