Ring expansion in the coupling of Fischer-carbene complexes with 1-alkynyl-1-hydroxy cyclic compounds

Date

2001-06-01

Author

Zora, Metin
Herndon, JW
Li, YH
Rossi, J

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

3
views

0
downloads

The coupling of a variety of transition metal-carbene complexes with alkynols has been studied. In many cases, the intermediate vinylcarbene complexes formed in this reaction undergo a ring expansion to afford cyclic ketone derivatives. This scope and limit of this process is explored.

Subject Keywords

Ring expansion, Carbene complexes, Alkynols

URI

https://hdl.handle.net/11511/55530

Journal

TETRAHEDRON

DOI

https://doi.org/10.1016/s0040-4020(01)00359-3

Collections

Department of Chemistry, Article