Synthesis of a new system containing a pyramidalized double bond: Lack of reactivity of a strongly protected pyramidalized double bond

Date

2001-01-01

Author

Saracoglu, N
Balcı, Metin

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The chemical reactivity of syn-3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemical reactions. To determine the reactivity of this central double bond. we synthesized syn- and anti-7 and recorded their photoelectron spectra. Low first-ionization potentials of syn- and anti-7 (7.6 eV) dearly indicated that these compounds should be highly reactive.

Subject Keywords

CYCLOHEPTATRIENE-NORCARADIENE EQUILIBRIUM, PHOTOELECTRON-SPECTRA, ELECTRONIC CONTROL, ABINITIO, STEREOSELECTIVITY, SESQUINORBORNENE, SPECTROSCOPY, NORBORNENE, OXIDATION, ENERGIES

URI

https://hdl.handle.net/11511/55920

Journal

HELVETICA CHIMICA ACTA

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

N. Saracoglu and M. Balcı, “Synthesis of a new system containing a pyramidalized double bond: Lack of reactivity of a strongly protected pyramidalized double bond,” HELVETICA CHIMICA ACTA, pp. 707–714, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55920.