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A convenient and selective synthesis of unsymmetrical benzoins via the cyanide ion catalyzed cleavage of benzils
Date
2004-04-19
Author
Demir, Ayhan Sıtkı
Reis, O
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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The cyanide ion-catalyzed cleavage of benzils is used for the generation of various 'masked' acyl intermediates. The reaction of these intermediates with various aldehydes furnishes the corresponding esters Of unsymmetrical benzoins in very good yields. A variety of unsymmetrical benzoin derivatives are synthesized in this way, including ferrocene derivatives. The hydrolysis of benzoin esters and their subsequent oxidation affords the corresponding unsymmetrical benzoins and benzils in high yield.
Subject Keywords
Organic Chemistry
,
Biochemistry
,
Drug Discovery
URI
https://hdl.handle.net/11511/56335
Journal
TETRAHEDRON
DOI
https://doi.org/10.1016/j.tet.2004.03.016
Collections
Department of Chemistry, Article