Synthesis and chiral recognition properties of two novel chiral calix[4]arene tartaric ester derivatives

Date

2006-08-14

Author

Karakucuk, Aysegul
Durmaz, Mustafa
Sirit, Abdulkadir
Yilmaz, Mustafa
Demir, Ayhan Sıtkı

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Two new chiral calix[4]arene derivatives containing tartaric acid ester moieties were synthesized. The chiral calix[4]arenes are in a 'cone' conformation according to NMR spectroscopy. The chiral recognition capabilities of 1-4 toward the guests, 1,2-propanediol and serine methyl ester hydrochloride (SerOMe), were investigated (H-1 NMR spectroscopy). The extraction properties of compounds 1 and 2 toward selected alpha-amino acid methyl esters were also studied.

Subject Keywords

Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Catalysis

URI

https://hdl.handle.net/11511/57652

Journal

TETRAHEDRON-ASYMMETRY

DOI

https://doi.org/10.1016/j.tetasy.2006.07.011

Collections

Department of Chemistry, Article

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Citation Formats

A. Karakucuk, M. Durmaz, A. Sirit, M. Yilmaz, and A. S. Demir, “Synthesis and chiral recognition properties of two novel chiral calix[4]arene tartaric ester derivatives,” TETRAHEDRON-ASYMMETRY, pp. 1963–1968, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/57652.