Role of copper species in the oxidative dimerization of arylboronic acids: Synthesis of symmetrical biaryls

Date

2003-12-26

Author

Demir, Ayhan Sıtkı
Reis, O
Emrullahoglu, M

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Certain Cu(I) and Cu(II) salts are able to mediate the dimerization of arylboronic acids in DMF. They provide the corresponding symmetrical biaryls in moderate to very good yields. It is possible to run the reaction catalytically under an oxygen atmosphere without a significant loss of yields.

Subject Keywords

C-N, Aryl, Iodides, Substitution, Temperature, Arylation, Radicals, Halides

URI

https://hdl.handle.net/11511/58005

Journal

JOURNAL OF ORGANIC CHEMISTRY

DOI

https://doi.org/10.1021/jo034680a

Collections

Department of Chemistry, Article

Citation Formats

A. S. Demir, O. Reis, and M. Emrullahoglu, “Role of copper species in the oxidative dimerization of arylboronic acids: Synthesis of symmetrical biaryls,” JOURNAL OF ORGANIC CHEMISTRY, vol. 68, no. 26, pp. 10130–10134, 2003, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/58005.