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Role of copper species in the oxidative dimerization of arylboronic acids: Synthesis of symmetrical biaryls
Date
2003-12-26
Author
Demir, Ayhan Sıtkı
Reis, O
Emrullahoglu, M
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
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Certain Cu(I) and Cu(II) salts are able to mediate the dimerization of arylboronic acids in DMF. They provide the corresponding symmetrical biaryls in moderate to very good yields. It is possible to run the reaction catalytically under an oxygen atmosphere without a significant loss of yields.
Subject Keywords
C-N
,
Aryl
,
Iodides
,
Substitution
,
Temperature
,
Arylation
,
Radicals
,
Halides
URI
https://hdl.handle.net/11511/58005
Journal
JOURNAL OF ORGANIC CHEMISTRY
DOI
https://doi.org/10.1021/jo034680a
Collections
Department of Chemistry, Article