SYNTHESIS OF ALPHA'-ACYLOXY ENONES FROM ENONES USING MANGANESE(III) ACETATE IN COMBINATION WITH MANGANESE(II) CARBOXYLATES OR CARBOXYLIC-ACIDS

Date

1989-08-18

Author

Demir, Ayhan Sıtkı
JEGANATHAN, A
WATT, DS

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Subject Keywords

Organic Chemistry

URI

https://hdl.handle.net/11511/58054

Journal

JOURNAL OF ORGANIC CHEMISTRY

DOI

https://doi.org/10.1021/jo00278a006

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Department of Chemistry, Article

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OXIDATION OF ARYL ALKYL KETONES TO ALPHA-ACYLOXY, ALPHA-(CAMPHORSULFONYLOXY), OR ALPHA-HYDROXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS OR (1S)-(+)-10-CAMPHORSULFONIC ACID DEMIR, AS; CAMKERTEN, N; AKGUN, H; Tanyeli, Cihangir; MAHASNEH, AS; WATT, DS (Informa UK Limited, 1990-01-01) The α-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, α-(10-camphorsulfonyloxy), and α-hydroxy derivatives in good yield.
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Citation Formats

A. S. Demir, A. JEGANATHAN, and D. WATT, “SYNTHESIS OF ALPHA’-ACYLOXY ENONES FROM ENONES USING MANGANESE(III) ACETATE IN COMBINATION WITH MANGANESE(II) CARBOXYLATES OR CARBOXYLIC-ACIDS,” JOURNAL OF ORGANIC CHEMISTRY, pp. 4020–4022, 1989, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/58054.