Cyclacenes having dislocated rings

Date

2001-02-23

Author

Türker, Burhan Lemi

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Clockwise and anticlockwise dislocation operation on cyclacenes were defined. Certain types of dislocated cyclacenes were subjected to AMI type semiempirical molecular orbital calculations in order to get some idea about these nonexistent structures. They were predicted to be more stable than the isomeric cyclacenes. The cryptoannulenic effect, which is the characteristic feature of the cyclacenes. subsides or disappears depending on the type of the dislocated system.

Subject Keywords

Cyclacenes, Cryptoannulenic effect, Dislocated cyclacenes, Pseudocyclacenes, AM1 calculations

URI

https://hdl.handle.net/11511/62316

Journal

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM

DOI

https://doi.org/10.1016/s0166-1280(00)00635-7

Collections

Department of Chemistry, Article

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Citation Formats

B. L. Türker, “Cyclacenes having dislocated rings,” JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, pp. 235–241, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/62316.