The influence of Ba(PO3)(2) on the formation characteristics of fluorophosphate glasses

Date

1998-01-01

Author

Ozturk, A

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Formation characteristics of glasses in the system AlF3 - MF2 - Ba(PO3)(2)(M=Ca, Mg, Sr, Ba) have been studied as a function of Ba(PO3)(2) content. Glass formation tendency increased with increasing Ba(PO3)(2). The critical cooling rate, R-c, for glass formation decreased from Rc 98 +/- 7 to 2 +/- 0.5 degrees C s(-1) when the Ba(PO3)(2) content of the glass increased from 0 to 1.5 mol%. The improvement in glass formation caused by Ba(PO3)(2) was due to linking of the broken chains present in the structure. The infrared transmission spectra of these glasses and their crystallization products suggested that the structure changed from short chains of AlF6 groups to long chains of PO3F and Ba(Ca, Mg, Sr)P2O7 groups with increasing Ba(PO3)(2) content of the glass.

Subject Keywords

Silica glasses, Crystallization, Kinetics

URI

https://hdl.handle.net/11511/64156

Journal

JOURNAL OF MATERIALS SCIENCE

DOI

https://doi.org/10.1023/a:1004337411440

Collections

Department of Metallurgical and Materials Engineering, Article

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Citation Formats

A. Ozturk, “The influence of Ba(PO3)(2) on the formation characteristics of fluorophosphate glasses,” JOURNAL OF MATERIALS SCIENCE, pp. 73–76, 1998, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/64156.