Kinetics of thermal decomposition of Hekimhan-Deveci siderite ore samples

Date

2008-07-02

Author

Alkac, Dilek
Atalay, Ümit

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Different solid-state reaction models, by interpretation of the model graphs in terms of goodness of fit to real data points (R-squared), are used to evaluate the reaction mechanism and the kinetics (E, n) for the thermal decomposition of Hekimhan-Deveci siderite ore samples. Isothermal experiments at three different temperatures (T=505 degrees C, 520 degrees C, 535 degrees C) are run for t=15-150 minutes while non-isothermal experiments are conducted at single heating rate (10 degrees C/min) using thermogravimetric analysis (TGA). Three-dimensional diffusion reaction models have been noted as the solid-state reaction model representing thermal decomposition kinetics of Hekimhan-Deveci siderite. The values of activation energy (E), the optimum kinetics obtained, are E=85.53 kj/mol (Jander three-dimensional diffusion reaction model); E=85.49 kj/mol, (Ginstling-Brounshtein three-dimensional diffusion reaction model).

Subject Keywords

Geotechnical Engineering and Engineering Geology, Geochemistry and Petrology

URI

https://hdl.handle.net/11511/65192

Journal

INTERNATIONAL JOURNAL OF MINERAL PROCESSING

DOI

https://doi.org/10.1016/j.minpro.2008.02.007

Collections

Department of Mining Engineering, Article

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Citation Formats

D. Alkac and Ü. Atalay, “Kinetics of thermal decomposition of Hekimhan-Deveci siderite ore samples,” INTERNATIONAL JOURNAL OF MINERAL PROCESSING, pp. 120–128, 2008, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/65192.