Diamminebis(2,4,6-tribromophenol-ato-O)copper(II)

Date

2000-06-01

Author

Tatar, L
Gokagac, G
Ulku, D

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The title compound, [Cu(C6H2Br3O)(2)(NH3)(2)], a monomeric centrosymmetric Cu-II complex, crystallizes in the monoclinic system. The CuO2N2 coordination sphere is trans planar, [Cu-O 1.943 (5) Angstrom and Cu-N 1.977 (6) Angstrom], with the fifth and sixth coordination sites occupied by Br atoms from the phenoxide ions [Cu-Br 3.129 (1) Angstrom], resulting in an elongated distorted octahedral structure for the CuO2N2Br2 coordination. Each of the NH3 groups forms two hydrogen bonds with the Br and O atoms of the CuO2N2Br2 moiety of a neighbouring molecule. This arrangement constitutes a one-dimensional chain along the x axis of the unit cell.

Subject Keywords

Cyclic voltammetry, Solid-state, Electro-initiated polymerization, Ethylenediamine copper(ii) complex

URI

https://hdl.handle.net/11511/66568

Journal

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

Collections

Department of Chemistry, Article

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Citation Formats

L. Tatar, G. Gokagac, and D. Ulku, “Diamminebis(2,4,6-tribromophenol-ato-O)copper(II),” ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, pp. 668–669, 2000, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/66568.