PHOTO-CHEMICAL ADDITION OF CONJUGATED DIENES TO TRICARBONYL-NU-1,3,5-CYCLOHEPTATRIENECHROMIUM(O)

Date

1978-01-01

Author

Özkar, Saim
NEUGEBAUER, D
KREITER, CG

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Conjugated dienes, e.g. 1,3-butadiene or trans, trans-2,4-hexadiene, undergo [4s + 6s] cycloaddition with tricarbonyl-η-1,3,5-cycloheptatrienechromium(0) (I) on irradiation with UV light in n-pentane at 263 K, and the bright red tricarbonyl-η-bicyclo[4.4.1]undeca-1,3,7-trienechromium(O) complexes Cr(CO)3C11H14 (II) and Cr(CO)3C13H18 (III) are formed in high yields. The structures of II and III were determined by IR, NMR and mass spectra and confirmed by an X-ray structure analysis for III.

URI

https://hdl.handle.net/11511/70013

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY

DOI

https://doi.org/10.1016/s0022-328x(00)91205-1

Collections

Department of Chemistry, Article

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Citation Formats

S. Özkar, D. NEUGEBAUER, and C. KREITER, “PHOTO-CHEMICAL ADDITION OF CONJUGATED DIENES TO TRICARBONYL-NU-1,3,5-CYCLOHEPTATRIENECHROMIUM(O),” JOURNAL OF ORGANOMETALLIC CHEMISTRY, pp. 115–124, 1978, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/70013.