Mn OAc 3 promoted addition of an active methylene compound to alkenes mechanistic studies

2015-11-11
Ceyhan, Selin
Çetinkaya, Yasin
Akdağ, Akın
Balcı, Metin

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Mn(OAc)3 promoted addition of an active methylene compound to alkenes: mechanistic studies
Ceyhan, Selin; Balcı, Metin; Department of Chemistry (2015)
Radical cyclization of alkenes is one of the most important methods for the synthesis of cyclic compounds. The one electron oxidant Mn(OAc)3 has been used for many years for the oxidative addition of acetic acid to alkenes to give lactones. In this thesis, various alkenes substituted at 1,2-positions by phenyl and thiophene rings were reacted with active methylene compounds in the presence of Mn(OAc)3∙2H2O. The regioselectivity of the addition were searched. The mechanism for the addition was studied in con...
Citation Formats
S. Ceyhan, Y. Çetinkaya, A. Akdağ, and M. Balcı, “Mn OAc 3 promoted addition of an active methylene compound to alkenes mechanistic studies,” 2015, Accessed: 00, 2021. [Online]. Available: http://www.tramech8.org/default.aspx?ID=4.