Oleosome based structures for designing new food products

2017-06-23

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Oleylamine-stabilized ruthenium(0) nanoparticles were in situ generated from the reduction of ruthenium(III) chloride by dimethylamine-borane during its dehydrogenation at room temperature. Nearly monodispersed ruthenium(0) nanoparticles of 1.8 +/- 0.7 nm size were reproducibly isolated from the reaction solution by filtration and characterized by TEM, XRD, HRTEM, B-11 NMR, ATR-IR and UV-visible spectroscopy. Oleylamine-stabilized ruthenium(0) nanoparticles are highly active catalyst in hydrogen generation ...
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Copper(0) nanoparticles, in situ generated from the reduction of copper(II) 2-ethylhexanoate during the dehydrogenation of dimethylamine borane (DMAB) at 50.0 +/- 0.1 degrees C in toluene solution, are active catalysts in hydrogen generation from DMAB, but not very stable against agglomeration. Addition of 5.0 equivalents of oleylamine (OAm) was found to stabilize copper(0) nanoparticles noticeably, while maintaining high catalytic activity. Oleylamine-stabilized copper(0) nanoparticles could be isolated fr...
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Citation Formats
B. Mert, “Oleosome based structures for designing new food products,” 2017, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/78629.