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Oleosome based structures for designing new food products
Date
2017-06-23
Author
Mert, Behiç
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https://hdl.handle.net/11511/78629
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Oleylamine-stabilized ruthenium(0) nanoparticles were in situ generated from the reduction of ruthenium(III) chloride by dimethylamine-borane during its dehydrogenation at room temperature. Nearly monodispersed ruthenium(0) nanoparticles of 1.8 +/- 0.7 nm size were reproducibly isolated from the reaction solution by filtration and characterized by TEM, XRD, HRTEM, B-11 NMR, ATR-IR and UV-visible spectroscopy. Oleylamine-stabilized ruthenium(0) nanoparticles are highly active catalyst in hydrogen generation ...
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Palladium(0) nanoclusters having an average particle size of 3.2 nm were generated in situ from the reduction of palladium(II) acetylacetonate in the presence of oleylamine (OAm) during the dehydrogenation of ammonia borane (AB) in THF under inert gas atmosphere at room temperature. OAm-stabilized palladium(0) nanoclusters were stable enough to be isolated as solid materials and characterized by TEM, HRTEM, XRD, UV-vis, and FT-IR techniques. They were found to be highly active catalysts in the hydrogen gene...
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Copper(0) nanoparticles, in situ generated from the reduction of copper(II) 2-ethylhexanoate during the dehydrogenation of dimethylamine borane (DMAB) at 50.0 +/- 0.1 degrees C in toluene solution, are active catalysts in hydrogen generation from DMAB, but not very stable against agglomeration. Addition of 5.0 equivalents of oleylamine (OAm) was found to stabilize copper(0) nanoparticles noticeably, while maintaining high catalytic activity. Oleylamine-stabilized copper(0) nanoparticles could be isolated fr...
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Increasing concern about the pollution of environment by inorganic and organic chemicals arising from naturally occurring ecological events and industrial processes has created a need for the search of new techniques in the removal of these contaminants. One of the natural material that can be used in such processes is clay. Clay minerals have large surface areas and high cation exchange capacities which enables them to be modified by cationic surfactants. The material prepared, often called as ءorganoclay̕...
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B. Mert, “Oleosome based structures for designing new food products,” 2017, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/78629.