2,1,3-Benzooxadiazole, thiophene and benzodithiophene based random copolymers for organic photovoltaics:Thiophene versus thieno[3,2-b]thiophene as π-conjugated linkers

2017-04-02
Göker, Seza
Hızalan Özsoy, Gönül
Aktaş, Ece
Kutkan, Seza
Çırpan, Ali
Toppare, Levent Kamil

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2,1,3-Benzooxadiazole, thiophene and benzodithiophene based random copolymers for organic photovoltaics: thiophene versus thieno[3,2-b]thiophene as pi-conjugated linkers
Goker, SEZA; HIZALAN, Gonul; AKTAS, Ece; KUTKAN, Seda; Çırpan, Ali; Toppare, Levent Kamil (Royal Society of Chemistry (RSC), 2016-12-01)
Three conjugated random copolymers comprising benzodithiophene and thiophene as the donor units and benzooxadiazole as the acceptor unit, spaced with thiophene and thieno[3,2-b]thiophene pi-bridges, were designed and synthesized. The effects of different linkers on the optical and electrochemical properties were investigated. The polymer containing a thieno[3,2-b]thiophene pi-bridge revealed a red shifted absorption compared to its thiophene analogue. Morphological and photovoltaic properties of a polymer:f...
2,1,3-Benzooxadiazole, thiophene and benzodithiophene based random copolymers for organic photovoltaics: Thiophene versus thieno[3,2-b]thiophene as pi-conjugated linkers
Göker, Seza; Hizalan, Gonul; Aktas, Ece; Kutkan, Seda; Çırpan, Ali; Toppare, Levent Kamil (2017-04-02)
Three conjugated random copolymers comprising benzodithiophene and thiophene as the donor units and benzooxadiazole as the acceptor unit, spaced with thiophene and thieno[3,2-b]thiophene π-bridges, were designed and synthesized. The effects of different linkers on the optical and electrochemical properties were investigated. The polymer containing a thieno[3,2-b]thiophene π-bridge revealed a red shifted absorption compared to its thiophene analogue. Morphological and photovoltaic properties of a polymer:ful...
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Bacilysin is a dipeptide antibiotic composed of L-alanine and L-anticapsin. We recently reported partial purification and characterization of the bacilysin synthetase. In the present study, L-anticapsin in the in vitro reaction mixture was replaced by furfurylamine, norephedrine, glycine, and benzylamine, respectively. The enzymatic biosynthesis of novel structures was checked by TLC analyses of reaction mixture extracts and any positive TLC result was verified by GC-MS analysis. The enzyme was shown to lin...
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The photooxygenation of 1,4-cyclohexadiene (3) affords the diastereomeric hydroperoxy endoperoxides exo-4 and endo-4 and the diastereomeric hydroperoxides trans-5 and cis-5 in a ratio of 87: 9:3.5:0.5. Selective reduction of hydroperoxide group in the endoperoxides exo-4 and endo-4 in the presence of titanium tetraisopropoxide-diethyl sulfide gave the corresponding hydroxy endoperoxides exo-7 and endo-7, which on PCC oxidation leads to the phenol-derived keto endoperoxide 2. The triphenylphosphine deoxygena...
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In this study, 2-amino-2-deoxy-glucose (2DG) was conjugated to COOH modified cobalt ferrite magnetic nanoparticles (COOH-MNPs), which were designed to target tumor cells as a potential targetable drug/gene delivery agent for cancer treatment. According to our results, it is apparent that, 2DG labeled MNPs were internalized more efficiently than COOH-MNPs under the same conditions in all cell types (MDA-MB-231 and MCF-7 cancer and MCF-10A normal breast cells) (p < 0.001). Moreover, the highest amount of upta...
Citation Formats
S. Göker, G. Hızalan Özsoy, E. Aktaş, S. Kutkan, A. Çırpan, and L. K. Toppare, “2,1,3-Benzooxadiazole, thiophene and benzodithiophene based random copolymers for organic photovoltaics:Thiophene versus thieno[3,2-b]thiophene as π-conjugated linkers,” 2017, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/80516.