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Methane production enhanced through ozone pretreatment in anaerobic digestion
Date
2018-09-23
Author
Tuncay, Sera
İçgen, Bülent
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https://hdl.handle.net/11511/83856
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Methane activation with bromine followed by the condensation of the methyl bromide into higher hydrocarbons or oxygenates is a novel route. However, the selective production of monobrominated methane (CH3Br) at high conversions is a crucial prerequisite. A reaction model was developed according to the kinetic data available in the literature and thoroughly studied to investigate the optimum reactor conditions for selective methane bromination in gas phase. It was concluded that at high methane (>90%) conver...
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Activation of methane with a halogen followed by the metathesis of methyl halide is a novel route from methane to higher hydrocarbons or oxygenates. Thermodynamic analysis revealed that bromine is the most suitable halogen for this goal. Analysis of the published data on the reaction kinetics in a CSTR enabled us to judge on the effects of temperature, reactor residence time and the feed concentrations of bromine and methane to the conversion of methane and the selectivity towards mono or dibromomethane. Th...
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S. Tuncay and B. İçgen, “Methane production enhanced through ozone pretreatment in anaerobic digestion,” 2018, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/83856.