The Alfa-Oxidation of alfa-acetoxy and alfa-alkoxy enones using Manganese (III) acetate in combination with carboxylic acids

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1992

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Saatçioğlu, Arman

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https://hdl.handle.net/11511/8902

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Graduate School of Natural and Applied Sciences, Thesis

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THE ALPHA'-OXIDATION OF ALPHA-ALKOXY ENONES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS Demir, Ayhan Sıtkı; SAATCIOGLU, A (Informa UK Limited, 1993-01-01) The alpha'-oxidation of cyclic derivatives of alpha-alkoxy-alpha,beta-unsaturated ketones using manganese(III)acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-2-alkoxy-2-cyclopentenones and 6-acyloxy-2-alkoxy-2-cyclohexenones.
The bridged even cyclacenes: AM1 treatment Türker, Burhan Lemi (Elsevier BV, 2003-08-01) Certain Huckel type even cyclacenes having one (S-R-type) or two (P-R- and C-R-types) -CH2CH2- bridge(s) are considered for AMI (RHF) type semiempirical quantum chemical calculations. In P-R-type structures the bridges connect two benzenoid rings of the corresponding cyclacene in such a way that an embedded para-cyclophane skeleton happens. The C-R-types contain two phane bridges which are crossly oriented. All these structures considered were found to be stable but endothermic in nature. Also, it has been ...
THE MILD N-NITROSATION OF SECONDARY-AMINES WITH TRICHLORONITROMETHANE Demir, Ayhan Sıtkı; MAHASNEH, AS; AKSOY, H; GERCEK, Z (Informa UK Limited, 1992-01-01) Reaction of trichloronitromethane with secondary amine leads to the formation
THE OXIDATION OF BETA-ALKOXYCYCLOPENTENONES AND BETA-ALKOXYCYCLOHEXENONES TO ALPHA'-ACYLOXY DERIVATIVES USING MANGANESE(III) ACETATE IN COMBINATION WITH CARBOXYLIC-ACIDS Demir, Ayhan Sıtkı; SAYRAC, T; WATT, DS (1990-12-01) The alpha-oxidation of cyclic derivatives of beta-alkoxy-alpha, beta-unsaturated ketones using manganese (III) acetate in the presence of various carboxylic acids provided a convenient synthesis of 5-acyloxy-3-alkoxy-2-cyclopentenones and 6-acyloxy-3-alkoxy-2-cyclohexenones.
The ortho- to meta- isomerization of dicarba-closo-dodecaborane Türker, Burhan Lemi (Elsevier BV, 2003-08-01) By means of AMI(RHF) type semiempirical quantum chemical calculations, the conversion of ortho- dicarba-closododecaborane to its meta- isomer is throughly investigated by considering two intermediate structures previously proposed.

Citation Formats

A. Saatçioğlu, “The Alfa-Oxidation of alfa-acetoxy and alfa-alkoxy enones using Manganese (III) acetate in combination with carboxylic acids,” Middle East Technical University, 1992.