Synthesis and characterization of arginine-doped heliotrope leaves with high clean-up capacity for crystal violet dye from aqueous media

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Date

2021-10-01

Author

Brini, Lahoucine
Hsini, Abdelghani
Naciri, Yassine
Bouzıanı, Asmae
Ajmal, Zeeshan
H'Maida, Khalihana
Boulahya, Aziz
Arahou, Mohamed
Bakiz, Bahcine
Albourine, Abdallah
Fekhaoui, Mohammed

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Novel an arginine-modified Heliotrope leaf (Arg@HL) was used as adsorbent for the crystal violet (CV) dye adsorption in a batch process. The physicochemical and morphological composition of Arg@HL were characterized by field-emission-scanning-electron-microscopy (FE-SEM), Fourier transforms infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC). The experiments were carried out to investigate the factors that influence the dye uptake by the adsorbent, such as the contact time under agitation, adsorbent amount, initial dye concentration, temperature and pH of dye solution. The optimum conditions of adsorption were found on the batch scale as followed: CV concentration of 20 mg center dot L-1, an amount of 0.75 g center dot L-1 of the adsorbent, 90 min contact time, 6 pH and 25 degrees C temperature for Arg@HL. The results confirmed a second-order model explaining the dye crystal violet's adsorption's kinetics by Arg-Heliotrope leaves. The Langmuir model effectively defines the adsorption isotherms. The results revealed that the Arg@HL has the potential to be used as a low-cost adsorbent for the removal of CV dye from aqueous solutions.

Subject Keywords

adsorption, Arg-Heliotrope leaves, arginine, isotherm, kinetics, thermodynamic

URI

https://hdl.handle.net/11511/93672

Journal

WATER SCIENCE AND TECHNOLOGY

DOI

https://doi.org/10.2166/wst.2021.446

Collections

Department of Chemical Engineering, Article

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Citation Formats

L. Brini et al., “Synthesis and characterization of arginine-doped heliotrope leaves with high clean-up capacity for crystal violet dye from aqueous media,” WATER SCIENCE AND TECHNOLOGY, pp. 0–0, 2021, Accessed: 00, 2021. [Online]. Available: https://hdl.handle.net/11511/93672.