Light induced step-growth polymerization of Donor-Acceptor-Donor (DAD) type monomers based on thiophene – [1,2,5] Chalcogenazolo[3,4-f]-benzo [1,2,3] triazole – Thiophene

Date

2021-12-01

Author

Kaya, Kerem
Aydan Alkan, Ecem
Yaşa, Mustafa
Süerkan, Ali
Udum, Yasemin
Toppare, Levent Kamil
Yağcı, Yusuf

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Two new donor-acceptor-donor(DAD) polymers type near-infrared (NIR) absorbing polymers containining thiophene as the donor and [1,2,5] chalcogenazolo [ 3,4-f]-benzo [1,2,3] triazole (chalcoen=S (P1a) or Se (P1b)) derivatives as the acceptor unit were designed and synthesized via light induced step-growth polymerization. The effect of different acceptor groups on the electrochemical and optical properties of the polymers was investigated. Highest occupied molecular orbital (HOMO) energy levels of the resultant black colored soluble polymers were calculated via cyclic voltammetry (CV) as −5.17 and −5.09eV for P1a and P1b, respectively. Optical electronic band gaps were calculated as 0.81 and 0.74eV for P1a and P1b, respectively. Lowest unoccupied molecular orbital (LUMO) energy levels were determined as −4.37 and −4.35eV for P1a and P1b, respectively. NMR and gel-permeation chromatography (GPC) results supported the formation of high-molecular weight species. Synthesized polymers have promising features for application in various optoelectronic devices.

URI

https://www.sciencedirect.com/science/article/pii/S0014305721005656?via%3Dihub
https://hdl.handle.net/11511/94376

Journal

European Polymer Journal

DOI

https://doi.org/10.1016/j.eurpolymj.2021.110831

Collections

Department of Chemistry, Article

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Citation Formats

K. Kaya et al., “Light induced step-growth polymerization of Donor-Acceptor-Donor (DAD) type monomers based on thiophene – [1,2,5] Chalcogenazolo[3,4-f]-benzo [1,2,3] triazole – Thiophene,” European Polymer Journal, vol. 161, no. 110831, pp. 1–7, 2021, Accessed: 00, 2021. [Online]. Available: https://www.sciencedirect.com/science/article/pii/S0014305721005656?via%3Dihub.