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N-aril rodanin ve N-aril 2.4 oksazolidindionların sentezleri ve spektroskopik yöntemler ile yapı analizleri
Date
1979-06-15
Author
İçli, Sıddık
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https://hdl.handle.net/11511/95643
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Department of Chemistry, Project and Design
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Asymmetric synthesis of N-aryl substituted chiral 1,4-aminoalcohol derivatives and applications in various asymmetric transformation reactions
Odabaş, Serhat; Tanyeli, Cihangir; Department of Chemistry (2007)
The asymmetric synthesis of N-aryl substituted chiral 1,4-aminoalcohols and their applications in asymmetric borane reduction and enantioselective diethylzinc addition to benzaldehyde reactions were performed starting from meso-anhydride 51 that is the cycloadduct of cyclopentadiene and maleic anhydride. The desymmetrization of meso-anhydride 51 was achieved by using quinine or quinidine with very high enantiomeric excess value (up to 98% ee) and with high chemical yield. The quinine-mediated desymmetrizati...
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Nucleophilic and electrophilic cyclization reactions of n-alkyne substituted pyrrole derivatives
Yenice, Işıl; Balcı, Metin; Department of Chemistry (2016)
Pyrrolopyrazinone, triazinone and oxazinone derivatives were synthesized via practical methodologies. In the study, N-alkyne substituted pyrrole esters were synthesized and isolated as key compounds via copper catalyzed cross-coupling reaction. Then, key compounds underwent nucleophilic cyclization reaction with hydrazine monohydrate to yield pyrrolopyrazinone and/or pyrrolotriazinone derivatives according to electronic properties of group attached to alkyne unit. Additional study was the synthesis of pyrro...
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N-Proparjilik β-Enaminon Bileşiklerinden 2-(İyodometilen)-2,3-dihidro-1,4-oksazepin Türevlerinin Sentezi
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S. İçli, “N-aril rodanin ve N-aril 2.4 oksazolidindionların sentezleri ve spektroskopik yöntemler ile yapı analizleri,” 1979. Accessed: 00, 2022. [Online]. Available: https://hdl.handle.net/11511/95643.