Negative-ion formation in fluoroacetonitrile and chloroacetonitrile following low-energy electron impact

Date

1988-12-09

Author

Hacaloğlu, Jale
Oster, Tatiana
Illenberger, Eugen

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CH2ClCN and CH2FCN show resonances near 3 and 8 eV, similar to those previously observed in CH3CN. In addition, both compounds capture electrons within a narrow resonance at very low energy (< 1 eV). While in CH2ClCN this low-energy negative-ion state is exclusively associated with Cl− formation, in CH2FCN a variety of fragment ions (F−, CN−, CHCN−, CHFCN−, CFCN−) are observed.

Subject Keywords

Chemistry, Physical, Physics, Atomic

URI

https://hdl.handle.net/11511/31712

Journal

Chemical Physics Letters

DOI

https://doi.org/10.1016/0009-2614(88)85224-2

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

J. Hacaloğlu, T. Oster, and E. Illenberger, “Negative-ion formation in fluoroacetonitrile and chloroacetonitrile following low-energy electron impact,” Chemical Physics Letters, pp. 268–272, 1988, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/31712.