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Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene: characterization and formation mechanism of the products
Date
2006-01-01
Author
Algi, Fatih
Balcı, Metin
Metadata
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Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene provided fluoro-indanes such as 4,6-difluoro-5-phenylindane, 5,6-difluoro-4-phenylindane, 5,7-difluoro-4-phenylindane, 4-bromo-6-fluoro-5-phenylindane and 5-bromo-6-fluoro-4-phenylindane. The characterization the formation mechanism of the products are discussed.
Subject Keywords
Bromofluorocarbene
,
Fluoro-indanes
,
Carbene addition
URI
https://hdl.handle.net/11511/54078
Journal
ARKIVOC
Collections
Graduate School of Natural and Applied Sciences, Article
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Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene: characterization and formation mechanism of the products
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Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene provided fluoro-indanes such as 4,6-difluoro-5-phenylindane, 5,6-difluoro-4-phenylindane, 5,7-difluoro-4-phenylindane, 4-bromo-6-fluoro-5-phenylindane and 5-bromo-6-fluoro-4-phenylindane. The characterization the formation mechanism of the products are discussed.
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A convenient new method for the arylation of furan and thiophene with arylhydrazine and manganese(III) acetate is described. Oxidation of arylhydrazines with Mn(III) acetate in furan or thiophene affords the corresponding 2-aryl-substituted furans and thiophenes in good yield using commercially available materials; access to 2-substituted heterobiaryls works selectively, and coupling occurs with loss of the hydrazine moiety.
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A convenient new method for the arylation of furan and thiophene with arylhydrazine and manganese(III) acetate is described. Oxidation of arylhydrazines with Mn(III) acetate in furan or thiophene affords the corresponding 2-aryl-substituted furans and thiophenes in good yield using commercially available materials; access to 2-substituted heterobiaryls works selectively, and coupling occurs with loss of the hydrazine moiety.
Photoinduced polymerization of thiophene using iodonium salt
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F. Algi and M. Balcı, “Bromofluorocarbene addition to 6-phenylbicyclo[3.2.0]hept-6-ene: characterization and formation mechanism of the products,”
ARKIVOC
, pp. 173–182, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/54078.