High temperature pyrolysis of poly(phenylene vinylene)s with poly(ε-caprolactone) or polystyrene side chains

Thermal degradation of poly(p-phenylene-graft-ε-caprolactone) copolymer Nur, Yusuf; Yurteri, Seda; Cianga, Ioan; Yagci, Yusuf; Hacaloğlu, Jale (2007-01-01) The thermal degradation of poly (p-phenylene-graft-epsilon-caprolactone) (PPP), synthesized by Suzuki polycondensation of poly(E-caprolactone) (PCL) with a central 2,5-dibromo-1,4-benzene on the chain with 1,4-phenylene-diboronic acid, has been studied via direct pyrolysis mass spectrometry. The thermal degradation occurred mainly in two steps. In the first step, decomposition of PCL chains occurred. A slight increase in thermal stability of PCL chains was noted. In the second stage of pyrolysis, the decomp...
Transformation of the caste system and the dalit movement Çalıkoğlu, Melih Rüştü; Soykut, Mustafa; Department of History (2005) This thesis analyzes the history of caste system and explains the theories of the birth of caste in Indian civilization. After defining the caste system in historical and cultural manner. examines the birth of and spreading of Dalit movement or low caste mass movement during the 19th and 20th century with the influence of British rule.
High temperature exposure of alkali-activated coal fly ashes Seyedian Choubi, Sepehr; Akgül, Çağla (2022-11-01) © 2022 Elsevier LtdThis study systematically investigates the impact of heat exposure on the performance of a wide range of alkali-activated coal fly ashes (AAF). Three low-Ca and three high-Ca coal fly ashes (CFAs) were activated with 10 M NaOH at an activator-to-CFA ratio of 0.5. Prepared pastes were cast into 5 × 5 × 5 cm cubes (for mechanical tests) and Φ6 × 4 cm cylinders (for thermal constant tests), cured at 80 °C for 24 h, and then stored in the fog room for 28 days. Samples were then exposed to 400...
Direct pyrolysis mass spectrometry studies on thermal degradation characteristics of poly(phenylene vinylene) with well-defined PSt side chains Nur, Y.; Çolak, Demet; Cianga, I.; Yagci, Y.; Hacaloğlu, Jale (2008-10-01) Thermal degradation characteristics of a new macromonomer polystyrene with central 4,4'-dicarbaldehyde terphenyl moieties and poly(phenylene vinylene) with well-defined polystyrene (PPV/PSt) as lateral substituents were investigated via direct pyrolysis mass spectrometry. A slight increase in thermal stability of PSt was detected for (PPV/PSt) and attributed to higher thermal stability of PPV backbone. It was almost impossible to differentiate products due to the decomposition of PPV backbone from those pro...
High quantum efficiency Type-II superlattice N-structure photodetectors with thin intrinsic layers ERGÜN, YÜKSEL; Hostut, Mustafa; Tansel, Tunay; Muti, Abdullah; KILIÇ, ABİDİN; Turan, Raşit; Aydinli, Atilla (2013-05-03) We report on the development of InAs/AlSb/GaSb based N-structure superlattice pin photodiode. In this new design, AlSb layer in between InAs and GaSb layers acts as an electron barrier that pushes electron and hole wave functions towards the GaSb/InAs interface to perform strong overlap under reverse bias. Experimental results show that, with only 20 periods of intrinsic layers, dark current density and dynamic resistance at -50 mV bias are measured as 6x10(-3) A/cm(2) and 148 Omega cm(2) at 77K, respective...

Citation Formats

Y. Nur, D. Çolak, I. Cianga, Y. Yagci, and J. Hacaloğlu, “High temperature pyrolysis of poly(phenylene vinylene)s with poly(ε-caprolactone) or polystyrene side chains,” Journal of Thermal Analysis and Calorimetry, pp. 527–532, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/31489.