N,N-diethyl-N '-benzoylthiourea - A new spectrophotometric reagent for rhenium determination

Date

2001-05-01

Author

Merdivan, M
Aygün, Rüveyde Sezer

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The reagent N,N-diethyl-N'-benzoylthiourea produces a green complex with rhenium in hydrochloric acid medium in the presence of tin(II) chloride. The complex extracted into toluene shows an absorption maximum at 383 nm, obeys Beer's law from 1.5 to 22 mug ml(-1) of rhenium while its molar absorptivity and Sandell sensitivity are 6.66 x 10(3) L mol(-1) cm(-1) and 0.028 mug cm(-2), respectively. It tolerates the presence of a large number of ions, including Mo(VI), W (VI) and some platinum metals. Job's and the mote ratio methods indicate that the rhenium metal and the chelating agent ratio of 1:2 in solution. The system has been applied to the determination of rhenium on synthetic samples and alumina based catalysts.

Subject Keywords

Spectrophotometric reagent, Rhenium determination, N,N-diethyl-N '-benzoylthiourea

URI

https://hdl.handle.net/11511/53203

Journal

ANNALI DI CHIMICA

Collections

Department of Chemistry, Article

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Citation Formats

M. Merdivan and R. S. Aygün, “N,N-diethyl-N ’-benzoylthiourea - A new spectrophotometric reagent for rhenium determination,” ANNALI DI CHIMICA, pp. 305–312, 2001, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/53203.