Serendipity in the Reactions of Indole-3-carboxaldehyde with Grignard Reagents

Date

2017-03-01

Author

Swager, Tımothy M.
Dengiz, Çağatay

Metadata

Show full item record

Item Usage Stats

47
views

0
downloads

URI

https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1590049
https://hdl.handle.net/11511/78228

Journal

Synfacts

Collections

Unverified, Article

Suggestions

OpenMETU
Core

Carboligation reactions with benzaldehyde lyase immobilized on superparamagnetic solid support Sopaci, S. Betuel; Turan, Ilke Simsek; Tural, Bilsen; Volkan, Mürvet; Demir, Ayhan Sıtkı (Royal Society of Chemistry (RSC), 2009-01-01) Histidine-tagged recombinant benzaldehyde lyase (BAL, EC 4.1.2.38) was efficiently immobilized to surface-modified magnetic particles with affinity ligand binding. In addition to conventional benzoin condensation reactions, two important representative BAL-catalyzed carboligation reactions, were also performed with this magnetically responsive biocatalyst. The results obtained from the carboligation reactions that were performed with this simple and convenient heterogenous biocatalyst were comparable to tha...
Substituent effects in hofmann type compounds of pyridine derivatives. Varman, Nilgün; Department of Chemistry (1980)
Stereoselective additions to the cyclobutene double bond via homoconjugation. Tanlak, Melek; Department of Chemistry (1977)
Stereoselective additions to the norbornene double bond via bishomoconjugation. Bozoğlu, Faruk; Department of Chemistry (1977)
Palladium-catalyzed formation of oxazolidinones from biscarbamates: a mechanistic study Kilbas, Benan; Balci, Metin (Beilstein Institut, 2011-2-24) Oxazolidinones can be synthesized starting from cyclic biscarbamates via a palladium-catalyzed reaction. To test the proposed mechanism of this reaction, first, bicyclonorcarene endoperoxides derived from cyano and carbomethoxy cycloheptatrienes were synthesized and converted into the corresponding diols. The reaction of diols with toluenesulfonyl isocyanate followed by a palladium catalyzed reaction furnished oxazolidinone derivatives in similar yields. It was shown that, if one face of the double bond is ...

Citation Formats

T. M. Swager and Ç. Dengiz, “Serendipity in the Reactions of Indole-3-carboxaldehyde with Grignard Reagents,” Synfacts, pp. 255–255, 2017, Accessed: 00, 2021. [Online]. Available: https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1590049.