Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
Effect of Pt nanoparticle size on resistance to chloride-induced inhibition for hydrodechlorination of trichloroethylene in water
Date
2024-04-01
Author
Karahan, Selin
Çelik, Gökhan
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
61
views
0
downloads
Cite This
Catalysts used for hydrodechlorination (HDC) of trichloroethylene (TCE) undergo partial or complete loss of catalytic activity due to inhibition by inevitable reaction product HCl. Changing the size of Pt NPs could be used as a strategy to prevent inhibition of HDC catalysts if the structure sensitivity of the reaction was known. This study aims to obtain structure-sensitivity of aqueous-phase HDC of TCE and investigate the effect of Pt NPs’ size on resistance to chloride inhibition. The research encompassed the synthesis of Pt NPs, characterization studies, and catalytic activity measurements at 30 °C & 1 atm H2 in batch or discontinuous pulse mode. Characterization results showed that targeted Pt NPs were successfully synthesized with average particle sizes of 3.0 nm, 5.8 nm, 8.9 nm, and 60.9 nm. Catalytic activity experiments revealed that initial turnover frequency values exhibited a decrease with increasing particle size of Pt NPs, indicating that aqueous-phase HDC of TCE is a structure sensitive reaction. The fastest kinetics and the highest resistance to HCl inhibition were observed over the smallest Pt NPs employed in this study. This information can serve as a rational synthesis parameter for designing catalysts that could mitigate chloride inhibition caused by the reaction product HCl.
Subject Keywords
Deactivation
,
Hydrodechlorination
,
Inhibition
,
Structure sensitivity
,
Trichloroethylene
URI
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85187924104&origin=inward
https://hdl.handle.net/11511/109277
Journal
Journal of Environmental Chemical Engineering
DOI
https://doi.org/10.1016/j.jece.2024.112467
Collections
Department of Chemical Engineering, Article
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
S. Karahan and G. Çelik, “Effect of Pt nanoparticle size on resistance to chloride-induced inhibition for hydrodechlorination of trichloroethylene in water,”
Journal of Environmental Chemical Engineering
, vol. 12, no. 2, pp. 0–0, 2024, Accessed: 00, 2024. [Online]. Available: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85187924104&origin=inward.