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Thermal degradation of polysiloxane and polyetherester containing benzoxazine moieties in the main chain
Date
2011-01-01
Author
Bagherifam, Shahla
Kışkan, Barış
Aydogan, Binnur
Yagci, Yusuf
Hacaloğlu, Jale
Metadata
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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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In this study investigation of thermal characteristics of polysiloxane and polyetherester containing benzoxazine moieties in the main chain was performed via pyrolysis mass spectrometry. Pyrolysis mass spectrometry analyses revealed that the thermal stability and the extent of cross-linking enhanced when the benzoxazine moieties were separated by thermally more stable units such as siloxanes. However, when the siloxane chain units were long, possibility of polybenzoxazine growth decreased significantly and benzoxazine moieties were evolved in the temperature range where polysiloxane degradation took place. (C) 2010 Elsevier B.V. All rights reserved. Keywords
Subject Keywords
Thermal degradation
,
Pyrolysis
,
Thermosets
,
Polyesters
,
Polysiloxanes
,
Polybenzoxazine
URI
https://hdl.handle.net/11511/29942
Journal
Journal of Analytical and Applied Pyrolysis
DOI
https://doi.org/10.1016/j.jaap.2010.12.001
Collections
Graduate School of Natural and Applied Sciences, Article
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S. Bagherifam, B. Kışkan, B. Aydogan, Y. Yagci, and J. Hacaloğlu, “Thermal degradation of polysiloxane and polyetherester containing benzoxazine moieties in the main chain,”
Journal of Analytical and Applied Pyrolysis
, pp. 155–163, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/29942.