Show/Hide Menu
Hide/Show Apps
Logout
Türkçe
Türkçe
Search
Search
Login
Login
OpenMETU
OpenMETU
About
About
Open Science Policy
Open Science Policy
Open Access Guideline
Open Access Guideline
Postgraduate Thesis Guideline
Postgraduate Thesis Guideline
Communities & Collections
Communities & Collections
Help
Help
Frequently Asked Questions
Frequently Asked Questions
Guides
Guides
Thesis submission
Thesis submission
MS without thesis term project submission
MS without thesis term project submission
Publication submission with DOI
Publication submission with DOI
Publication submission
Publication submission
Supporting Information
Supporting Information
General Information
General Information
Copyright, Embargo and License
Copyright, Embargo and License
Contact us
Contact us
A conducting composite of polythiophene: Synthesis and characterization
Download
index.pdf
Date
1996-01-01
Author
Vatansever, Fatma
Hacaloğlu, Jale
Akbulut, Ural
Toppare, Levent Kamil
Metadata
Show full item record
This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
.
Item Usage Stats
195
views
0
downloads
Cite This
Conducting polymer composites of polythiophene, using a polyamide as the insulating matrix, were prepared via electrochemical methods. The characterization of the composite was done by scanning electron microscopy, differential scanning calorimetry, thermogravimetric analysis, Fourier transform infrared and pyrolysis studies. The conductivities were measured by a four-probe technique. The cited methods revealed that the composites have properties different from those of simple mechanical mixtures of the two polymers.
Subject Keywords
Conducting polymer composite
,
Polythiophene
,
Pyrolysis
,
Mass spectrometry
URI
https://hdl.handle.net/11511/30453
Journal
Polymer International
DOI
https://doi.org/10.1002/(sici)1097-0126(199611)41:3<237::aid-pi587>3.0.co;2-0
Collections
Graduate School of Natural and Applied Sciences, Article
Suggestions
OpenMETU
Core
A pyrolysis mass spectrometry study of polythiophene - Natural rubber and polythiophene - Synthetic rubber conducting polymer composites
Yigit, S.; Hacaloğlu, Jale; Akbulut, Ural; Toppare, Levent Kamil (1997-01-01)
The thermal behaviors and degradation products of conducting polymer composites prepared by electrooxidation of thiophene using natural rubber or synthetic rubber as the insulating matrix were studied by direct and indirect mass spectrometry techniques. The pyrolysis mass data revealed that a chemical interaction formed between the components of the composites during polymerization. Thermal characteristics of rubbers totally disappeared in the composites indicating presence of some chain scissions leading t...
A pyrolysis mass spectrometry study of polythiophene-polyamide composites
Vatansever, F.; Akbulut, Ural; Toppare, Levent Kamil; Hacaloğlu, Jale (1996-01-01)
The thermal behavior of composites of polythiophene and polyamide prepared by mechanical blending and electrochemical synthesis of polythiophene onto an electrode coated with polyamide have been studied thoroughly by the pyrolysis approach under both direct and indirect pyrolysis mass spectrometric analysis conditions. It is determined that the electrolytic film has different properties from the mechanical mixture and the related homopolymers.
Characterization of conducting copolymer of thiophene via pyrolysis mass spectrometry
Levent, Anil; Hacaloğlu, Jale; Toppare, Levent Kamil (2005-12-01)
In this work, structural and thermal characterization of a conducting copolymer of thiophene (PTh) with 2-methylbutyl-2-(3-thienyl)acetate prepared by two different methods has been performed by pyrolysis mass spectrometry techniques. The pyrolysis mass spectrometry data of both components of the copolymer, polythiophene, PTh, poly(2-methylbutyl-2-(3-thienyl)acetate), PMBTA and PTh/PMBTA have been analyzed and compared. It has been determined that when the electrochemical polymerization of thiophene was ach...
Characterization of conducting copolymers of succinic acid bis-(-4-pyrrol-1-yl-phenyl) ester and thiophene via pyrolysis mass spectrometry
Ertas, Merve; Hacaloğlu, Jale; Toppare, Levent Kamil (2005-03-01)
In this work, a direct pyrolysis mass spectrometry technique was applied to characterize a conducting copolymer of succinic acid bis-(4-pyrrol-1-yl-phenyl) ester (SM) and thiophene prepared by electrochemical polymerization. Thermal degradation behavior of both components was quite similar to those of the corresponding homopolymers, PSM, and polythiophene PTh. Yet, detection of oligomers and mixed dimers of both monomers in the high temperature pyrolysis mass spectra confirmed the formation of a copolymer. ...
Characterization of conducting copolymer of pyrrole via pyrolysis mass spectrometry
Levent, Anil; Hacaloğlu, Jale; Toppare, Levent Kamil (2008-03-01)
In this work, structural and thermal characterization of BF4- doped copolymer of pyrrole (PPy) with 2-methylbutyl-2-(3-thienyl)acetate prepared by electrochemical polymerization were performed via a pyrolysis mass spectrometry technique. The pyrolysis mass spectrometry data of the copolymer PPy/PMBTA, and the homopolymers; polypyrrole, PPy, and poly(2-methylbutyl-2-(3-thienyl)acetate), PMBTA were analyzed and compared. It has been determined that when the electrochemical polymerization of pyrrole was achiev...
Citation Formats
IEEE
ACM
APA
CHICAGO
MLA
BibTeX
F. Vatansever, J. Hacaloğlu, U. Akbulut, and L. K. Toppare, “A conducting composite of polythiophene: Synthesis and characterization,”
Polymer International
, pp. 237–244, 1996, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/30453.