Chemical ionization discharge of N2O for matrix infrared spectroscopic study of isolated anions

Date

1990-12-01

Author

Hacaloğlu, Jale
Andrews, Lester

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A Townsend discharge chemical ionization source has been used for matrix infrared studies of anions in the argon-N20 system. In addition to neutral products, the NO", N02", (NO)f, NN02", and 03" anions have also been isolated. Filtered visible photolysis shows different behaviors for these anions. The two isomers NN02" and (NO)2" have been identified by isotopic substitution and characterized by different 15N and 180 isotopic shifts and different structures. These matrix isolation experiments provide structural information on two different N202" stoichiometry anions observed in mass spectroscopy experiments.

URI

https://hdl.handle.net/11511/32561

Journal

Journal of Physical Chemistry

DOI

https://doi.org/10.1021/j100368a011

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Graduate School of Natural and Applied Sciences, Article

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Citation Formats

J. Hacaloğlu and L. Andrews, “Chemical ionization discharge of N2O for matrix infrared spectroscopic study of isolated anions,” Journal of Physical Chemistry, pp. 1759–1764, 1990, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/32561.