Pippard relations modified by the Raman frequency shifts for the phases I and II in NH4I

Date

2009-04-30

Author

Yurtseven, Hasan Hamit

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Pippard relations in terms of the frequency shifts of the v(7) (40 cm(-1)) lattice mode, are established here for the phases I and II in NH4I. The temperature-induced frequency shift, (1/v)(partial derivative v/partial derivative T)(P) is calculated through the isobaric mode Gruneisen parameter gamma(P) using the lattice parameter data at zero pressure for the phases I and II in NH4I. From the frequency shifts, the specific heat C-P is calculated for the phases studied at zero pressure. Also, the pressure-induced frequency shift, (1/v)(partial derivative v/partial derivative P)(T) is calculated through the isothermal mode Gruneisen parameter gamma(T) at 300 K and it is related to the thermal expansivity alpha(P) for the phases I and II in NH4I.

Subject Keywords

Inorganic Chemistry, Organic Chemistry, Analytical Chemistry, Spectroscopy

URI

https://hdl.handle.net/11511/46539

Journal

JOURNAL OF MOLECULAR STRUCTURE

DOI

https://doi.org/10.1016/j.molstruc.2008.10.070

Collections

Department of Physics, Article

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Citation Formats

H. H. Yurtseven, “Pippard relations modified by the Raman frequency shifts for the phases I and II in NH4I,” JOURNAL OF MOLECULAR STRUCTURE, pp. 540–543, 2009, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/46539.