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T-P Phase Diagram of Nitrogen at High Pressures
Date
2018-05-01
Author
Algul, G.
Enginer, Y.
Yurtseven, Hasan Hamit
Metadata
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This work is licensed under a
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License
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By employing a mean field model, calculation of the T-P phase diagram of molecular nitrogen is performed at high pressures up to 200 GPa. Experimental data from the literature are used to fit a quadratic function in T and P, describing the phase line equations which have been derived using the mean field model studied here for N-2, and the fitted parameters are determined. Our model study gives that the observed T-P phase diagram can be described satisfactorily for the first-order transitions between the phases at low as well as high pressures in nitrogen. Some thermodynamic quantities can also be predicted as functions of temperature and pressure from the mean field model studied here and they can be compared with the experimental data.
Subject Keywords
First-order transition
,
Mean field model
,
Nitrogen
,
T-P phase diagram
URI
https://hdl.handle.net/11511/46588
Journal
INTERNATIONAL JOURNAL OF THERMOPHYSICS
DOI
https://doi.org/10.1007/s10765-018-2376-1
Collections
Department of Physics, Article