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Stereoregular polymerization of methylmethacrylate by atom transfer radical polymerization
Date
2006-01-01
Author
Aran, B
Usanmaz, Ali
Metadata
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Methyl methacrylate (MMA) was polymerized by the atom transfer radical polymerization (ATRP) method to obtain living low molecular weight polymers. The initiator was p-toluenesulfonylchloride and the catalyst ligand complex system was CuCl-4,4'dimethyl 2,2'bipyridine. Polymers with controlled molecular weight were obtained. The polymer chains were shown by NMR spectrum to be mostly syndiotactic. The molecular weight distributions were measured by the GPC method. The K and a constants in [eta] = KM alpha equation were measured as 9.13 x 10(-5) and 0.74, respectively. FT- IR and X-Ray results showed steororegularity in polymer chains. The thermal properties were studied by DSC and molecular weight-glass transition temperature relations were determined.
Subject Keywords
Materials Chemistry
,
General Chemistry
,
Polymers and Plastics
,
Ceramics and Composites
URI
https://hdl.handle.net/11511/51524
Journal
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
DOI
https://doi.org/10.1080/10601320500437086
Collections
Graduate School of Natural and Applied Sciences, Article
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B. Aran and A. Usanmaz, “Stereoregular polymerization of methylmethacrylate by atom transfer radical polymerization,”
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
, pp. 233–245, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51524.