Cettaertalyst-Free Hydrogenation of Alkenes and Alkynes with Hydrazine in the Presence of Oxygen

Date

2014-03-17

Author

Menges, Nurettin
Balcı, Metin

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A series of alkenes and alkynes was subjected to reduction with hydrazine hydrate in ethanol in the presence of oxygen. An efficient method was developed for the reduction of C-C double bonds and C-C triple bonds with diimide, generated in situ from hydrazine hydrate by oxidation with oxygen. The reduction process proceeded for 24-48 hours with high chemoselectivity and excellent yields. This reduction procedure offers synthetic advantages over metal-catalyzed hydrogenation as well as other systems.

Subject Keywords

Organic Chemistry

URI

https://hdl.handle.net/11511/51800

Journal

SYNLETT

DOI

https://doi.org/10.1055/s-0033-1340554

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

N. Menges and M. Balcı, “Cettaertalyst-Free Hydrogenation of Alkenes and Alkynes with Hydrazine in the Presence of Oxygen,” SYNLETT, pp. 671–676, 2014, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/51800.