An investigation of the formation mechanism of allene or alkyne in the 6,7-benzobicyclo[3,2.1]octane system by deuterium labeling experiments

Date

1999-01-01

Author

Taskesenligil, Y
Tumer, F
Kazaz, C
Balcı, Metin

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In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benaobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. Reaction of 10 with potassium tert-butoxide yielded butoxyl ether 18 in which proton-deuterium exchange has occured.

Subject Keywords

Cyclic allene, Cyclic alkynes, Deuterium labeling

URI

https://hdl.handle.net/11511/54972

Journal

TURKISH JOURNAL OF CHEMISTRY

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

Y. Taskesenligil, F. Tumer, C. Kazaz, and M. Balcı, “An investigation of the formation mechanism of allene or alkyne in the 6,7-benzobicyclo[3,2.1]octane system by deuterium labeling experiments,” TURKISH JOURNAL OF CHEMISTRY, pp. 115–122, 1999, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/54972.