Chemistry of bicyclic endoperoxides derived from dihydropyridine derivatives: Attempted synthesis of polyhydroxypiperidine derivatives

Date

2006-01-01

Author

Salamci, Emine
Bayram, Beyhan
Balcı, Metin

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To achieve the synthesis of azasugar derivatives with the utilization of singlet oxygen, pyridine was used as the starting material. The reduction of pyridine followed by a singlet oxygen reaction afforded cyclic aza-endoperoxides (14 and 16). However, many attempts were made to convert the azaendoperoxides to the corresponding di- and triacetates without success. However, the base-catalyzed rearrangement of 14 gave unprecedented rearrangement products 23 and 24.

Subject Keywords

Azasugar derivatives, Amino sugars, Singlet oxygen, Bicyclic endoperoxides

URI

https://hdl.handle.net/11511/55974

Journal

TURKISH JOURNAL OF CHEMISTRY

Collections

Graduate School of Natural and Applied Sciences, Article

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Citation Formats

E. Salamci, B. Bayram, and M. Balcı, “Chemistry of bicyclic endoperoxides derived from dihydropyridine derivatives: Attempted synthesis of polyhydroxypiperidine derivatives,” TURKISH JOURNAL OF CHEMISTRY, pp. 441–449, 2006, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/55974.